Fabrication of Comb-type self-oscillating gels by atom transfer radical polymerization for controlling autonomous swelling/deswelling behavior
نویسندگان
چکیده
Abstract In this study, we show the controlled self-oscillation behavior (i.e., normalized amplitude, swelling rate, and deswelling rate) of self-oscillating gels by introducing grafted chains. The chain was introduced to base gel network “grafting from” method atom-transfer radical polymerization (ATRP). We demonstrated that properties chain, including monomer composition length can lead notable behavior. strategy in study pave way for realizing desirable operational functions biomimetic actuators.
منابع مشابه
Macromolecular engineering by atom transfer radical polymerization.
This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water. The roles of the major components of ATRP--monomers, initiato...
متن کاملModification of Polyvinyl Alcohol via Atom Transfer Radical Polymerization for Targeted Drug Delivery Applications
In current study,a hydrogel based on biocompatible polymerwas prepared. The functionalization of polyvinyl alcohol (PVA)with epichlorohydrin(ECH) to produce epichlorohydrin-g-polyvinyl alcohol (PVA/ECH) as a suitable macroinitiator for atom transfer radical polymerization (ATRP) reaction was investigated.ThenN-vinyl pyrrolidone (NVP) waspolymerized on the surface of macroinitiatorin presence of...
متن کاملMathematical Modeling of Atom Transfer Radical Polymerization
............................................................................................................................. iii Acknowledgments............................................................................................................... v Table of
متن کاملMetal-free atom transfer radical polymerization.
Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and chain ends of the resulting polymers. Signifi...
متن کاملNanostructured hybrid hydrogels prepared by a combination of atom transfer radical polymerization and free radical polymerization.
A new method to prepare nanostructured hybrid hydrogels by incorporating well-defined poly(oligo (ethylene oxide) monomethyl ether methacrylate) (POEO(300)MA) nanogels of sizes 110-120 nm into a larger three-dimensional (3D) matrix was developed for drug delivery scaffolds for tissue engineering applications. Rhodamine B isothiocyanate-labeled dextran (RITC-Dx) or fluorescein isothiocyanate-lab...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Npg Asia Materials
سال: 2022
ISSN: ['1884-4049', '1884-4057']
DOI: https://doi.org/10.1038/s41427-022-00360-0